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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Refinery Sources
Catalytic Cracking
Thermal Operations
Coproduct from Ethylene Production
Ethylene Oligomerization
alpha-Olefin Production
Ethylene Dimerization
Dehydrogenation of n-Butane and Isobutane
Dehydration of tert-Butyl Alcohol to Isobutylene
Cracking of Methyl tert-Butyl Ether
Hydrogenation of C4 Hydrocarbons
Isomerization of n-Butenes to Isobutylene
Uses
Fuel Uses
Dimersol
Gasoline Alkylate
MTBE (Methyl tert-Butyl Ether) and ETBE (Ethyl tert-Butyl Ether)
Polymer Gasoline
Direct Blending
Other Fuel Uses
Chemical Uses
Chemical Uses for n-Butenes
Butadiene
Butene-1
Polyethylene copolymer
Polybutene-1
Valeraldehyde
1,2-Butylene oxide
Other butene-1 uses
Butene-2
sec-Butyl Alcohol
Polygas and Dimersol Chemicals
Chemical Uses for Isobutylene
High-Purity Isobutylene Derivatives
Butyl rubber
Methyl methacrylate (MMA)
Polyisobutylenes
Substituted phenols
Other high-purity isobutylene uses
Polybutenes
Chemical Uses for Diisobutylene and Triisobutylene
Supply and Demand by Region
United States
Producing Companies
Refinery Butylenes
Ethylene Coproduct
High-Purity Butylenes
Production
Refinery Operations
Ethylene Coproduct
Production of Isomers
Consumption
Fuel Applications
Gasoline alkylate
Polymer gasoline and dimersol
MTBE
ETBE
Other fuel uses
n-Butenes for Chemical Consumption
Butene-1
sec-Butyl alcohol
Polygas and dimersol chemicals
Butadiene
Butene-2
Isobutylene for Chemical Consumption
Polybutenes
High-purity isobutylene derivatives
Diisobutylene and triisobutylene
Price
Gasoline and Other Alternative Fuel Values
High-Purity Isobutylene Values
Trade
Canada
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Butane Dehydrogenation
Production
Consumption
Fuel Applications
Alkylation
MTBE
Chemical Applications
Price
Trade
Mexico
Central and South America
Western Europe
Producing Companies
Refinery Butylenes
Ethylene Coproduct
High-Purity Butylenes
Production
Consumption
Fuel Applications
Alkylation
MTBE
Polygas blending
Chemical Consumption
sec-Butyl alcohol
Butene-1
High-purity isobutylene
Price
Trade
Central and Eastern Europe
Middle East
Japan
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Producers of Butylenes for Chemicals
Production
Consumption
Motor Fuel Applications
Alkylation
Polymer gasoline and dimersol
MTBE
Chemical Consumption
Price
Trade
Other Regions
Other Asia
Oceania
Africa
   
  Butylenes
   
  Ed Sporcic and Koon Ling Ring and Masahiro Yoneyama
  Published December 2005
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  Abstract
   
 

Butylenes are four-carbon mono-olefins that find uses in fuel and chemical applications. Fuel markets account for about 90% of the world production of butylenes. The major fuel application is in the manufacture of gasoline blending components, such as gasoline alkylate, polymer gasoline and dimersol. Isobutylene serves as a raw material for the oxygenates, methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE). Butylenes may also be blended directly into gasoline for volatility control. They are also marketed with propane and butanes as liquefied petroleum gas (LPG).

Total world consumption of butylenes in 2004 was over 44 million metric tons. At about 10% of the total worldwide market for butylenes, the size of the chemical market for butylenes pales in comparison to that of the fuel market. n-Butenes are used as the precursor for sec-butyl alcohol, butadiene, butene-1 and other smaller applications. In the developed regions, the chemical market for n-butenes is growing slowly. There are segments like butene-1 that continue to demonstrate modest growth, but the majority of the n-butenes market is stagnant or declining. Similarly, chemical markets for isobutylene have grown slowly, especially because the consumption of MTBE in the United States slowed during 1999–2004 and is now projected to decline or be banned; other isobutylene derivatives such as butyl rubber and polybutenes are mature markets.

The following pie charts show world production and consumption of butylenes in 2004.

 

In the United States, chemical demand for n-butenes is expected to increase at only 0.7% per year during 2004–2009 despite moderate growth for butene-1. MTBE consumption is expected to decline sharply as a result of legislation against the use of MTBE in gasoline in California and several other states, and the possibility of a nationwide MTBE ban. Western European consumption of n-butenes for chemical use will grow at an average rate of 0.8% per year, while isobutylene use (excluding MTBE) will increase at roughly 1% per year during 2004–2009. The expected use of isobutylene for ETBE is expected to grow more rapidly; however, this will depend on various government policies. Japan’s chemical markets for n-butenes and isobutylene will average 0.6% and 0.2% annual growth, respectively, during 2004–2009.

The other important areas for butylenes are South and Central America, the Middle East, and Other Asia. In general, these areas have relatively small butylenes consumption for chemicals, but use large quantities of butylenes for fuel applications, particularly MTBE.

 
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