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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Liquid-Phase Oxidation of Ethylene
From Ethyl Alcohol
Acetylene Hydration
Environmental issues
Supply and Demand by Region
United States
Producing Companies
Industry Structure and Dynamics
Salient Statistics
Production
Consumption
Pyridines
Acetate Esters
Pentaerythritol
Peracetic Acid
1,3-Butylene Glycol (1,3-Butanediol)
Acetic Acid
Other
Price
Trade
Canada
Consumption
Trade
Mexico
Producing Companies
Production
Consumption
Acetic Acid
Ethyl Acetate
Ethanol
Other
Trade
South America
Producing Companies
Production
Western Europe
Producing Companies
Production
Consumption
Acetic Acid/Acetic Anhydride
Ethyl Acetate
Pentaerythritol
Synthetic Pyridines
Glyoxal/Glyoxylic Acid
Crotonaldehyde
Other
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
Producing Companies
Production
Consumption
Ethyl Acetate
Pentaerythritol
Acetic Acid
Other
Price
Trade
Other Asia
Producing Companies
China
   
  Acetaldehyde
   
  Michael Malveda and Kenji Fujita and Bala Suresh
  Published April 2007
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  Abstract
   
 

Demand for acetaldehyde worldwide has continued to decrease, primarily as a result of less consumption for acetic acid manufacture, as the industry moves toward the more efficient carbonylation-of-methanol process. All manufacture of acetic acid from acetaldehyde in North America has been discontinued and in Europe significant capacity has been permanently shut down. Acetaldehyde use for acetic acid manufacture in Asia continues but is under pressure and will decline because of the establishment of methanol carbonylation technology. Demand has also significantly declined in the production of plasticizer alcohols, which has switched completely to oxo processes. Since 1995, some 360 thousand metric tons of acetaldehyde capacity has been shut down in Western Europe, and Mexico has closed its acetaldehyde capacity. New acetaldehyde capacity has been installed in China, but this is the only world area where new capacity has been added.

Up to year-end 2000, Western Europe and China were the largest acetaldehyde-consuming regions. With the closure of Celanese AG’s European acetaldehyde–to–acetic acid operations, China has become the largest consumer. The demise of acetaldehyde–to–acetic acid operations has caused a major change in the captive/merchant ratio in North America and Europe, and merchant sales now represent the major volume.

The following pie chart shows consumption of acetaldehyde by major region:

The outlook for acetaldehyde is for continued closures of acetic acid–from–acetaldehyde operations in those areas where that process is currently used. In North America and Western Europe, this transition is already nearly complete. Acetaldehyde derivatives such as synthetic pyridines, pentaerythritol and in some cases acetate ester manufactured from acetaldehyde appear secure in North America, but there are no apparent new significantapplications that will result in major increased volumes of acetaldehyde. However, Europe has experienced declining demand for acetaldehyde for the production of acetic acid, ethyl acetate and pyridines, resulting from plant closures during the past three years. During 2006–2011, consumption of acetaldehyde in North America is expected to decline by about 2%, and in Europe, it is likely to fall marginally. In China, gradual decline in acetaldehyde consumption during this period will be seen because of the introduction of an advanced carbonylation process that obviates the need for the acetaldehyde process for the production of downstream derivatives.

 
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