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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Alcohol-Amine Reaction
Aldehyde-Amine and ketamine hydrogenation Reaction
Nitrile Reduction
Ritter Reaction
Direct Amination
Hydrogenation of Anilines
Reaction of alkyl halides with amines (or ammonia)
Environmental issues
Supply and Demand by Region
United States
Producing Companies
Production
Consumption
Methylamines
Methylamine
Dimethylamine
Trimethylamine
Ethylamines
Ethylamine
Diethylamine
Triethylamine
Propylamines
n-Propylamines
Isopropylamines
Butylamines
n-Butylamine
Di-n-butylamine
Tri-n-butylamine
Isobutylamines
t-Butylamine
Amylamines
Cyclohexylamines
Cyclohexylamine
N-Alkylcyclohexylamines
Other
Allyl and methallylamines
Miscellaneous
Price
Trade
Imports
Exports
Canada
Producing Companies
Consumption
Trade
Mexico
Producing Companies
Consumption
Trade
Imports
Exports
Brazil
Producing Companies
Production
Consumption
Trade
Western Europe
Producing Companies
Production
Consumption
Consumption by Application
Solvents
Agrochemicals
Feed additives
Rubber processing chemicals
Pharmaceuticals
Surfactants
Consumption by Product
Methylamines
Ethylamines
Propylamines
Butylamines
Cyclohexylamines
Price
Trade
Imports
Exports
Central and Eastern Europe
Producing Companies
Production
Consumption
Methylamines
Ethylamines
Propylamines
Butylamines
Cyclohexylamines
Trade
Japan
Producing Companies
Production
Consumption
Methylamines
Methylamine
Dimethylamine
Trimethylamine
Ethylamines
Propylamines
Butylamines
n-Butylamines
t-Butylamine
Cyclohexylamines
Price
Trade
Imports
Exports
Other Regions
China
Indonesia
Republic of Korea
South Africa
Taiwan
   
  Alkylamines (C1-C6)
   
  Phil Calderoni and Yoshio Inoguchi and Thomas Kaelin
  Published December 2005
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  Abstract
   
 

Individual C1-C6 alkyl monoamines (RNH2, R2NH, R3N) are used primarily as intermediates for a variety of important industrial products. In a few instances, the amines are used directly as corrosion inhibitors. Products covered in this report are purely alkylamines and not products that contain heteroatoms such as the alkanolamines. End-use products based on alkylamines include pesticides, solvents, water treating chemicals and rubber processing chemicals. The only significant similarity among the various alkylamines is that they are all amines, but each individual amine has its own set of applications.

The following pie chart shows world consumption of alkylamines in 2004:

The United States and Europe are the major producing and consuming regions for alkylamines. World consumption in 2004 amounted to more than 610 thousand metric tons.

Consumption of alkylamines can fluctuate annually, especially as related to varying production of pesticides. Some amines, such as isopropylamine from the United States and methylamines from Canada, have rather large export volumes; however, international trade is not a major factor in alkylamines generally. Several amine derivatives have substantial export volumes; examples are N-methylpyrrolidone and dimethylformamide.

Most applications for alkylamines are well established, and rapid growth is not expected for any individual amines in the near future. The rapid expansion of isopropylamine demand for glyphosate salt manufacture to be used on resistant crops will be delayed until consumer sentiment changes toward genetically engineered foods. Water treatment chemicals are an expanding application for dimethylamine. Worldwide growth in alkylamine demand should average a modest 2–3% annually from 2005 through 2009.

 

 
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